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        Cyclohexane

        Cyclohexane
        Cyclohexane structure
        CAS No.
        110-82-7
        Chemical Name:
        Cyclohexane
        Synonyms
        ohexane;NAPHTHENE;Cicloesano;Cyclohesan;cyclohexan;CYCLOHEXANE;cyclohexaan;Cykloheksan;hexamethylen;HEXAMETHYLENE
        CBNumber:
        CB4193601
        Molecular Formula:
        C6H12
        Formula Weight:
        84.16
        MOL File:
        110-82-7.mol

        Cyclohexane Properties

        Melting point:
        4-7 °C(lit.)
        Boiling point:
        80.7 °C(lit.)
        Density 
        0.779 g/mL at 25 °C(lit.)
        vapor density 
        2.9 (vs air)
        vapor pressure 
        168.8 mm Hg ( 37.7 °C)
        refractive index 
        n20/D 1.426(lit.)
        Flash point:
        -1 °F
        storage temp. 
        Store at RT.
        solubility 
        ethanol: miscible(lit.)
        form 
        Liquid
        color 
        colorless
        Relative polarity
        0.006
        Odor
        resembling benzene; mild, sweet, resembling chloroform.
        Odor Threshold
        2.5ppm
        explosive limit
        1.2-8.3%(V)
        Water Solubility 
        PRACTICALLY INSOLUBLE
        FreezingPoint 
        6.554℃
        λmax
        λ: 210 nm Amax: ≤1.00
        λ: 220 nm Amax: ≤0.50
        λ: 230 nm Amax: ≤0.20
        λ: 235 nm Amax: ≤0.10
        λ: 240 nm Amax: ≤0.08
        λ: 250 nm Amax: ≤0.03
        λ: 255 nm Amax: ≤0.01
        Merck 
        14,2723
        BRN 
        1900225
        Henry's Law Constant
        1.03, 1.26, 1.40, 1.77, and 2.23 at 10, 15, 20, 25, and 30 °C, respectively (EPICS, Ashworth et al., 1988) 0.54, 0.69, 0.82, 1.43, and 1.79 at 2.0, 6.0, 10.0, 18.0, and 25.0 °C, respectively (Dewulf et al.,1999)
        Exposure limits
        TLV-TWA 300 ppm (~1050 mg/m3) (ACGIH, OSHA, and NIOSH); IDLH 10,000 ppm (NIOSH).
        InChIKey
        XDTMQSROBMDMFD-UHFFFAOYSA-N
        FDA 21 CFR
        175.105; 176.200; 73.1
        CAS DataBase Reference
        110-82-7(CAS DataBase Reference)
        Substances Added to Food (formerly EAFUS)
        CYCLOHEXANE
        EWG's Food Scores
        2
        FDA UNII
        48K5MKG32S
        NIST Chemistry Reference
        Cyclohexane(110-82-7)
        EPA Substance Registry System
        Cyclohexane (110-82-7)
        SAFETY
        • Risk and Safety Statements
        Symbol(GHS) 
        GHS02,GHS07,GHS08,GHS09
        Signal word  Danger
        Hazard statements  H319-H335-H361-H371-H313-H400-H412-H225-H304-H315-H336-H410
        Precautionary statements  P301+P310a-P303+P361+P353-P405-P501a-P210-P261-P273-P301+P310-P331-P501-P370+P378-P403+P235-P201-P202-P233-P240-P241+P242+P243-P260-P264-P270-P271-P280-P302+P352+P332+P313+P362+P364-P304+P340+P312-P305+P351+P338+P337+P313-P308+P311-P391-P403+P233
        Hazard Codes  F,Xn,N
        Risk Statements  11-38-50/53-65-67-20
        Safety Statements  9-16-25-33-60-61-62
        RIDADR  UN 1145 3/PG 2
        WGK Germany  2
        RTECS  GU6300000
        3-10
        Autoignition Temperature 500 °F
        TSCA  Yes
        HS Code  2902 11 00
        HazardClass  3
        PackingGroup  II
        Toxicity LC in mice: ~60-70 mg/l air (Lazarew)
        NFPA 704
        3
        1 0

        Cyclohexane price More Price(66)

        Manufacturer Product number Product description CAS number Packaging Price Updated Buy
        Sigma-Aldrich 179191 Cyclohexane ACS reagent, ≥99% 110-82-7 1l $115 2020-08-18 Buy
        Sigma-Aldrich 1601408 Residual Solvent Class 2 - Cyclohexane United States Pharmacopeia (USP) Reference Standard 110-82-7 3x1.2ml $125 2020-08-18 Buy
        TCI Chemical C0696 Cyclohexane [for Spectrophotometry] >99.5%(GC) 110-82-7 100mL $45 2020-06-24 Buy
        TCI Chemical C0818 Cyclohexane [for HPLC Solvent] >99.5%(GC) 110-82-7 500mL $92 2020-06-24 Buy
        Alfa Aesar 022864 Cyclohexane, ACS, 99+% 110-82-7 1L $55.3 2020-06-24 Buy

        Cyclohexane Chemical Properties,Uses,Production

        Chemical Properties

        Cyclohexane is a colorless liquid with a mild, sweet odor.

        Physical properties

        Colorless liquid with a sweet, chloroform-like odor. A detection odor threshold concentration of 2,700 mg/m3 (784 ppmv) was experimentally determined by Dravnieks (1974). An odor threshold concentration of 2.7 ppbv was reported by Nagata and Takeuchi (1990).

        Uses

        Suitable for HPLC, spectrophotometry, environmental testing

        Uses

        Solvent for lacquers and resins. Paint and varnish remover. In the extraction of essential oils. In analytical chemistry for mol wt determinations (cryoscopic constant 20.3). In the manufacture of adipic acid, benzene, cyclohexyl chloride, nitrocyclohexane, cyclohexanol and cyclohexanone. In the manufacture of solid fuel for camp stoves. In fungicidal formulations (possesses slight fungicidal action). In the industrial recrystallization of steroids.

        Uses

        Cyclohexane is a petroleum product obtainedby distilling C4- 400°F boiling rangenaphthas, followed by fractionation andsuperfractionation; also formed by catalytichydrogenation of benzene. It is usedextensively as a solvent for lacquers andresins, as a paint and varnish remover, andin the manufacture of adipic acid, benzene,cyclohexanol, and cyclohexanone.

        Definition

        A colorless liquid alkane that is commonly used as a solvent and in the production of hexanedioic acid (adipic acid) for the manufacture of nylon. Cyclohexane, itself, is manufactured by the reformation of longer chain hydrocarbons present in crude-oil fractions. It is also interesting from a structural point of view, existing as a ‘puckered’ six-membered ring, having all bonds between carbon atoms at 109.9° (the tetrahedral angle). The molecule undergoes rapid interconversion between two ‘chair-like’ CONFORMATIONS, which are energetically equivalent, passing through a ‘boat-like’ structure of higher energy. It is commonly represented by a hexagon.

        Definition

        cyclohexane: A colourless liquidcycloalkane, C6H12; r.d. 0.78; m.p.6.5°C; b.p. 81°C. It occurs in petroleumand is made by passing benzeneand hydrogen under pressureover a heated Raney nickel catalyst at150°C, or by the reduction of cyclohexanone.It is used as a solvent andpaint remover and can be oxidizedusing hot concentrated nitric acid tohexanedioic acid (adipic acid). The cyclohexanering is not planar and canadopt boat and chair conformations;in formulae it is representedby a single hexagon.

        Definition

        ChEBI: An alicyclic hydrocarbon comprising a ring of six carbon atoms; the cyclic form of hexane, used as a raw material in the manufacture of nylon.

        Production Methods

        Cyclohexane is fractionated from crude oil and may be released wherever petroleum products are refined, stored, and used. Another large source of general release is in exhaust gases from motor vehicles. It is prepared synthetically from benzene, by hydrocracking of cyclopentane, or from toluene by simultaneous dealkylation and double bond hydrogenation.

        General Description

        A clear colorless liquid with a petroleum-like odor. Used to make nylon, as a solvent, paint remover, and to make other chemicals. Flash point -4°F. Density 6.5 lb / gal (less than water) and insoluble in water. Vapors heavier than air.

        Air & Water Reactions

        Highly flammable. Insoluble in water.

        Reactivity Profile

        Liquid nitrogen dioxide was fed into a nitration column containing hot Cyclohexane, due to an error. An explosion resulted [MCA Case History 128(1962)] Incompatible with strong oxidizers.

        Health Hazard

        Dizziness, with nausea and vomiting. Concentrated vapor may cause unconsciousness and collapse.

        Health Hazard

        Cyclohexane is an acute toxicant of loworder. It is an irritant to the eyes and respiratorysystem. Exposure to a 1–2% concentrationin air caused lethargy, drowsiness,and narcosis in test animals. The lethal concentrationfor a 1-hour exposure in mice isestimated at around 30,000 ppm. Ingestionof cyclohexane exhibited low toxic effects intest species. The LD50 values in the literature show a wide variation. It may be detectedfrom its odor at 300 ppm concentration.

        Chemical Reactivity

        Reactivity with Water: No reaction; Reactivity with Common Materials: No reaction; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

        Safety Profile

        Poison by intravenous route, Moderately toxic by ingestion. A systemic irritant by inhalation and ingestion. A skin irritant. Mutation data reported. Flammable liquid. Dangerous fire hazard when exposed to heat or flame; can react with oxidming materials. Moderate explosion hazard in the form of vapor when exposed to flame. When mixed hot with liquid dinitrogen tetraoxide an explosion can result. To fight fire, use foam, CO2, dry chemical, spray, fog. When heated to decomposition it emits acrid smoke and fumes.

        Potential Exposure

        Cyclohexane is used as a chemical intermediate; as a solvent for fats, oils, waxes, resins, cer- tain synthetic rubbers; and as an extractant of essential oils in the perfume industry.

        Carcinogenicity

        No tumor-promoting activity was observed in mice receiving one 60 mL application of 0.3% DMBA in benzene followed by a 60 mL application of cyclohexane twice weekly for 50 weeks.

        Source

        Schauer et al. (1999) reported cyclohexane in a diesel-powered medium-duty truck exhaust at an emission rate of 210 μg/km.
        California Phase II reformulated gasoline contained cyclohexane at a concentration of 8,900 mg/kg. Gas-phase tailpipe emission rates from gasoline-powered automobiles with and without catalytic converters were 1.44 and 238.0 mg/km, respectively (Schauer et al., 2002).

        Environmental Fate

        Biological. Microbial degradation products reported include cyclohexanol (Dugan, 1972; Verschueren, 1983), 1-oxa-2-oxocycloheptane, 6-hydroxyheptanoate, 6-oxohexanoate, adipic acid, acetyl-CoA, succinyl-CoA (quoted, Verschueren, 1983), and cyclohexanone (Dugan, 1972; Keck et al., 1989).
        Photolytic. The following rate constants were reported for the reaction of cyclohexane and OH radicals in the atmosphere: 5.38 x 10-12 cm3/molecule?sec at 295 K (Greiner, 1970); 6.7 x 10-12 cm3/molecule?sec at 300 K (Darnall et al., 1978); 6.69 x 10-12 cm3/molecule?sec at 298 (DeMore and Bayes, 1999); 7.0 x 10-12 cm3/molecule?sec (Atkinson et al., 1979); 7.49 x 10-12 cm3/molecule?sec (Atkinson, 1990). A photooxidation reaction rate constant of 1.35 x 10-16 cm3/molecule?sec was reported for the reaction of cyclohexane with NO3 in the atmosphere (Atkinson, 1991).
        Chemical/Physical. The gas-phase reaction of cyclohexane with OH radicals in the presence of nitric oxide yielded cyclohexanone and cyclohexyl nitrate as the major products (Aschmann et al., 1997).
        Cyclohexane will not hydrolyze because it has no hydrolyzable functional group.

        Shipping

        UN1145 Cyclohexane, Hazard Class: 3; Labels: 3-Flammable liquid.

        Purification Methods

        It is best to purify it by washing with conc H2SO4 until the washings are colourless, followed by water, aqueous Na2CO3 or 5% NaOH, and again water until neutral. It is then dried with P2O5, Linde type 4A molecular sieves, CaCl2, or MgSO4 then Na and distilled. Cyclohexane has been refluxed with, and distilled from Na, CaH2, LiAlH4 (which also removes peroxides), sodium/potassium alloy, or P2O5. Traces of *benzene can be removed by passage through a column of silica gel that has been freshly heated: this gives material suitable for ultraviolet and infrared spectroscopy. If there is much *benzene in the cyclohexane, most of it can be removed by a preliminary treatment with nitrating acid (a cold mixture of 30mL conc HNO3 and 70mL of conc H2SO4) which converts *benzene into nitrobenzene. The impure cyclohexane and the nitrating acid are placed in an ice bath and stirred vigorously for 15minutes, after which the mixture is allowed to warm to 25o during 1hour. The cyclohexane is decanted, washed several times with 25% NaOH, then water, dried with CaCl2, and distilled from sodium. Carbonyl-containing impurities can be removed as described for chloroform. Other purification procedures include passage through columns of activated alumina and repeated crystallisation by partial freezing. Small quantities may be purified by chromatography on a Dowex 710-Chromosorb W gas-liquid chromatographic column. Flammable liquid. [Sabatier Ind Eng Chem 18 1005 1926, Schefland & Jacobs The Handbook of Organic Solvents (Van Nostrand) p592 1953, Beilstein 5 IV 27.] Rapid purification: Distil, discarding the forerun. Stand distillate over Grade I alumina (5% w/v) or 4A molecular sieves.

        Incompatibilities

        May form explosive mixture with air. Contact with oxidizers, nitrogen dioxide, and oxygen can cause fire and explosion hazard. Can explode in heat when mixed with dinitrogen tetraoxide liquid.

        Waste Disposal

        Dissolve or mix the material with a combustible solvent and burn in a chemical incinera- tor equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

        Cyclohexane Preparation Products And Raw materials

        Raw materials

        Preparation Products


        Cyclohexane Suppliers

        Global( 384)Suppliers
        Supplier Tel Fax Email Country ProdList Advantage
        Shanghai Aladdin Bio-Chem Technology Co.,LTD 021-20337333-801
        021-50323701 market@aladdin-e.com China 24983 65
        Shanghai neon biological technology co., LTD 021-54252912-8903
        leona.xin@forneeds.cn China 4778 58
        Liaocheng Tongda Chemical Co. LTD
        18963573761 18963573761@163.com China 52 58
        VWR(Shanghai) Co., Ltd 400-821-8006
        +86-21-58558801 info_china@vwr.com China 3046 75
        Aikon International Limited 025-58859352-
        02557626880 hywu@aikonchem.com China 13940 58
        Nantong Runfeng Petrochemical Co., Ltd
        0513-55085866 2853167121@qq.com China 1012 58
        Jinan Trands Chemical Co. LTD 0531-88770911- ;0531-88770911-
        0531-88770911 277033665@qq.com;1343989492@qq.com China 78 58
        J & K SCIENTIFIC LTD. 010-82848833- ;010-82848833-
        86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96815 76
        Meryer (Shanghai) Chemical Technology Co., Ltd. 21-61259100-
        86-21-61259102 sh@meryer.com China 40268 62
        Alfa Aesar 400-610-6006; 021-67582000
        021-67582001/03/05 saleschina@alfa-asia.com China 30163 84

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        View Lastest Price from Cyclohexane manufacturers

        Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
        2020-01-06 Cyclohexane
        110-82-7
        US $1.00 / KG 1KG 99% 20T Shaanxi Dideu Medichem Co. Ltd
        2019-07-11 Cyclohexane
        110-82-7
        US $1.00 / KG 1KG 99% 25kg career henan chemical co
        2019-05-23 Cyclohexane
        110-82-7
        US $7.00 / KG 1KG 99% 100KG career henan chemical co

        Cyclohexane Spectrum


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