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        L-Tryptophan

        Description Overview Content analysis Application References
        L-Tryptophan
        L-Tryptophan structure
        CAS No.
        73-22-3
        Chemical Name:
        L-Tryptophan
        Synonyms
        TRP;eh121;L-Trp;L-Ttp;trofan;EH 121;Eltrip;Lyphan;Tryptan;H-TRP-OH
        CBNumber:
        CB3750054
        Molecular Formula:
        C11H12N2O2
        Formula Weight:
        204.23
        MOL File:
        73-22-3.mol

        L-Tryptophan Properties

        Melting point:
        289-290 °C (dec.)(lit.)
        alpha 
        -31.1 º (c=1, H20)
        Boiling point:
        342.72°C (rough estimate)
        Density 
        1.34
        refractive index 
        -32 ° (C=1, H2O)
        storage temp. 
        Store at RT.
        solubility 
        20% NH3: 0.1 g/mL at 20 °C, clear, colorless
        pka
        2.46(at 25℃)
        form 
        powder
        color 
        White to yellow-white
        PH
        5.5-7.0 (10g/l, H2O, 20℃)
        optical activity
        [α]20/D 31.5±1°, c = 1% in H2O
        Water Solubility 
        11.4 g/L (25 ºC)
        Merck 
        14,9797
        BRN 
        86197
        Stability:
        Stable. Incompatible with strong acids, strong oxidizing agents.
        InChIKey
        QIVBCDIJIAJPQS-VIFPVBQESA-N
        CAS DataBase Reference
        73-22-3(CAS DataBase Reference)
        NIST Chemistry Reference
        L-Tryptophan(73-22-3)
        EPA Substance Registry System
        L-Tryptophan (73-22-3)
        SAFETY
        • Risk and Safety Statements
        Hazard Codes  Xi
        Risk Statements  33-40-62-41-37/38-36/37/38-22
        Safety Statements  24/25-36/37/39-36-26
        WGK Germany  2
        RTECS  YN6130000
        8
        TSCA  Yes
        HS Code  29339990
        Toxicity LD508mmol / kg (rat, intraperitoneal injection). It is safe when used in food (FDA, §172.320, 2000).
        NFPA 704
        0
        1 0

        L-Tryptophan price More Price(33)

        Manufacturer Product number Product description CAS number Packaging Price Updated Buy
        Sigma-Aldrich 51145 L-Tryptophan certified reference material, TraceCERT 73-22-3 100mg $97.2 2019-12-02 Buy
        Sigma-Aldrich 1700501 L-Tryptophan United States Pharmacopeia (USP) Reference Standard 73-22-3 200mg $414.05 2019-12-02 Buy
        TCI Chemical T0541 L-Tryptophan >98.5%(HPLC)(T) 73-22-3 25g $29 2019-12-02 Buy
        TCI Chemical T0541 L-Tryptophan >98.5%(HPLC)(T) 73-22-3 100g $85 2019-12-02 Buy
        Alfa Aesar A10230 L-Tryptophan, 99% 73-22-3 100g $105 2019-12-02 Buy

        L-Tryptophan Chemical Properties,Uses,Production

        Description

        As an essential amino acid, L-Tryptophan is necessary for normal growth in infants and for nitrogen balance in adults, which cannot be synthesized from more basic substances in humans and other animals, suggesting that it is obtained only by intake of tryptophan or tryptophan-containing proteins for human body, which is particularly plentiful in chocolate, oats, milk, cottage cheese, red meat, eggs, fish, poultry, sesame, almonds, buckwheat, spirulina, and peanuts, etc. It can be used as a nutritional supplement for use as an antidepressant, anxiolytic, and sleep aid. Thus, L-Tryptophan can be used for depression, anxiety, sleep apnea, premenstrual syndrome and many other problems. Besides, it can also be used in managing pain tolerance and managing weight.
        It works by increasing the levels of certain neurotransmitters in the brain called serotonin. People suffer from depression have an imbalance of serotonin and other brain chemicals. Thus, the increase of serotonin levels in the brain can improve symptoms of depression. L-Tryptopan serves as the precursor for the synthesis of serotonin, which is converted to serotonin in the body. As a result, the symptoms of depression and other problems are improved.

        Overview

        It is also known as α-aminoindolylpropionic acid. Appearance: white to slightly yellowish white crystal or crystalline powder. No smell; Slight bitter taste. Melting temperature: 289 ° C (decomposition); soluble in water. Applications: as food fortifier, antioxidant; also used in medicine. It is manufactured from indole aldehyde, alternatively also be synthesized from trypsin decomposition and synthesis.

        Content analysis

        Accurately weigh about 300 mg sample and dissolve it in 3ml formic acid and 50ml glacial acetic acid; add 2 drops crystal violet test solution (TS-250), titrate with 0.1mol / L perchloric acid to the green end point or until the blue color completely disappears. Each Ml of 0.1 mol / L perchloric acid corresponds to 20.42 mg of L-tryptophan (C11H12N2O2).

        Application

        Amino acids-type drug:
        It can be used in amino acid infusion, being often combined with iron and vitamins. Its co-administration with VB6 can improve depression and prevention/treatment of skin disease; as a sleep sedative, it can be combined with L-dopa for the treatment of Parkinson's disease. It is carcinogenic to experimental animals; it may cause adverse reactions including nausea, anorexia and asthmas. Avoid combination with monoamine oxidase inhibitors.
        Nutritional supplements:
        Tryptophan contained in egg white protein, fish meat, corn meal and other amino acids are limited; content in cereals such as rice is also low. It can be combined with lysine, methionine and threonine for enhanced amino acids. It can be supplemented to corn product at the content of 0.02% tryptophan and 0.1% lysine, being capable of significantly improving the protein potency.

        References

        https://en.wikipedia.org/wiki/Tryptophan
        http://www.medicinenet.com/tryptophan-oral_capsule_tablet/article.htm
        http://bodyandhealth.canada.com/drug/getdrug/apo-tryptophan
        https://www.drugbank.ca/drugs/DB00150

        Chemical Properties

        White to off-white crystalline powder

        Chemical Properties

        Appearance: white crystalline powder. Odorless, slightly bitter taste;
        Solubility: slightly soluble in water (1.14%, 25 ℃), insoluble in ethanol; soluble in dilute acid or dilute alkali. mp 289 ° C (decomposition).
        Isoelectric point: 5.89. [α] D + 2.8 (5 mol / L HCl), [α] D + 6.2 (0.5 mol / L NaOH).
        It can be colored upon long-term exposure to light. Its co-heating reaction with water will generate a small amount of indole while heating in the presence of sodium hydroxide and copper sulfate will produce a large amount of indole. It is stable upon heating together with acid in the dark, but is easily to be decomposed when heated together with other amino acids, carbohydrates and aldehydes. L-tryptophan will be completely decomposed when applying acid to break down the protein.

        Uses

        adrenergic agonist

        Uses

        tryptophan is one of the 21 amino acids comprising a protein. Tryptophan is a component of the skin’s natural moisturizing factors.

        Definition

        ChEBI: The L-enantiomer of tryptophan.

        brand name

        Ardeytropin;Kalma;Optimax;Sedanoct.

        World Health Organization (WHO)

        L-tryptophan, an essential aminoacid and precursor of serotonin, was introduced into medicine in 1963 for the treatment of depression and sleep disorders. Its effectiveness in these conditions has, however, never been convincingly demonstrated. It is also widely used in dietary supplements, parenteral nutrition preparations and dietary products for children with phenylketonuria. In 1989, reports from the USA showed an association between the consumption of L-tryptophan containing preparations and the development of eosiniphilia-myalgia syndrome (EMS), a condition characterized by intense eosinophilia, severe muscle and joint pain, swelling of the arms and legs, skin rashes and possible fever. Some of the reported cases have been fatal. Since it is not yet clear whether L-tryptophan itself or an unidentified contaminant is the cause of the EMS, many drug regulatory authorities have suspended the marketing authorization of products containing tryptophan pending further investigation, whereas others have withdrawn these products or restricted their use.

        General Description

        White powder with a flat taste. An essential amino acid; occurs in isomeric forms.

        Air & Water Reactions

        Slightly soluble in water.

        Reactivity Profile

        Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides.

        Health Hazard

        ACUTE/CHRONIC HAZARDS: When heated to decomposition L-Tryptophan emits toxic fumes.

        Fire Hazard

        Flash point data for L-Tryptophan are not available. L-Tryptophan is probably combustible.

        Safety Profile

        Moderately toxic by intraperitoneal route. Experimental teratogenic and reproductive effects. Human mutation data reported. Questionable carcinogen with experimental tumorigenic data. When heated to decomposition it emits toxic fumes of NOx.

        Purification Methods

        Crystallise L-tryptophan from H2O/EtOH, wash it with anhydrous diethyl ether and dry it at room temperature in a vacuum over P2O5. It sublimes at 220-230o/0.03mm with 99% recovery and unracemised [Gross & Gradsky J Am Chem Soc 77 1678 1955]. [Cox & King Org Synth Coll Vol II 612 1943, Greenstein & Winitz The Chemistry of the Amino Acids J. Wiley, Vol 3 pp 2316-2345 1961, Beilstein 22 IV 6765.]

        L-Tryptophan Preparation Products And Raw materials

        Raw materials

        Preparation Products


        L-Tryptophan Suppliers

        Global( 591)Suppliers
        Supplier Tel Fax Email Country ProdList Advantage
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        86-21-61259102 sh@meryer.com China 40268 62
        INTATRADE GmbH +49 3493/605464
        +49 3493/605470 sales@intatrade.de Germany 3579 66
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        021-67582001/03/05 saleschina@alfa-asia.com China 30163 84
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        TCI (Shanghai) Development Co., Ltd. 021-67121386 / 800-988-0390
        021-67121385 Sales-CN@TCIchemicals.com China 24555 81
        Beijing dtftchem Technology Co., Ltd. 13651141086; 86(10)60275028、60275820
        86 (10) 60270825 dtftchem@sina.com China 3393 62

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        View Lastest Price from L-Tryptophan manufacturers

        Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
        2019-07-23 L-TRYPTOPHAN
        73-22-3
        US $1.00 / g 1g 99% 1000 Kilogram/Kilograms per Month Cangzhou Wanyou New Material Technology Co.,Ltd
        2018-08-02 L-Tryptophan
        73-22-3
        US $20.00 / KG 10KG 99% 20kg career henan chemical co
        2018-08-01 L-Tryptophan
        73-22-3
        US $150.00 / KG 1KG 99% 1000kg career henan chemical co

        L-Tryptophan Spectrum


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