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        4-Carboxyphenylboronic acid

        Description Reference
        4-Carboxyphenylboronic acid
        4-Carboxyphenylboronic acid structure
        CAS No.
        14047-29-1
        Chemical Name:
        4-Carboxyphenylboronic acid
        Synonyms
        NSC 221170;AURORA 14935;AKOS BRN-0008;WLN: VHOR DBQQ;ZERENEX ZX001647;4-borono-benzoicaci;TIMTEC-BB SBB003899;RARECHEM AH PB 0147;p-borono-benzoicaci;p-boronobenzoicacid
        CBNumber:
        CB1312607
        Molecular Formula:
        C7H7BO4
        Formula Weight:
        165.94
        MOL File:
        14047-29-1.mol

        4-Carboxyphenylboronic acid Properties

        Melting point:
        220 °C (dec.)(lit.)
        Boiling point:
        406.4±47.0 °C(Predicted)
        Density 
        1.40±0.1 g/cm3(Predicted)
        storage temp. 
        0-6°C
        pka
        4.08±0.10(Predicted)
        form 
        Powder
        color 
        Off-white to light beige
        BRN 
        3031088
        InChIKey
        SIAVMDKGVRXFAX-UHFFFAOYSA-N
        CAS DataBase Reference
        14047-29-1(CAS DataBase Reference)
        SAFETY
        • Risk and Safety Statements
        Symbol(GHS) 
        GHS07
        Signal word  Warning
        Hazard statements  H315-H319-H303-H335
        Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
        Hazard Codes  Xi,Xn
        Risk Statements  36/37/38-20/21/22
        Safety Statements  37/39-26-36
        WGK Germany  2
        RTECS  CY8925000
        Hazard Note  Irritant
        TSCA  No
        HazardClass  IRRITANT
        HS Code  29319090

        4-Carboxyphenylboronic acid price More Price(9)

        Manufacturer Product number Product description CAS number Packaging Price Updated Buy
        Sigma-Aldrich 456772 4-Carboxyphenylboronic acid 14047-29-1 1g $32.3 2019-12-02 Buy
        Sigma-Aldrich 456772 4-Carboxyphenylboronic acid 14047-29-1 10g $236 2019-12-02 Buy
        TCI Chemical C1353 4-Carboxyphenylboronic Acid (contains varying amounts of Anhydride) 14047-29-1 1g $31 2019-12-02 Buy
        TCI Chemical C1353 4-Carboxyphenylboronic Acid (contains varying amounts of Anhydride) 14047-29-1 5g $107 2019-12-02 Buy
        Alfa Aesar B20954 4-Carboxybenzeneboronic acid, 97% 14047-29-1 5g $114 2019-12-02 Buy

        4-Carboxyphenylboronic acid Chemical Properties,Uses,Production

        Description

        4-Carboxyphenylboronic acid is a highly versatile reagent. It is a reagent used in various reactions including condensation reactions with stabilizer chains at the surface of polystyrene latex, Suzuki coupling reactions, esterification, derivatization of polyvinylamine, synthesis of isotopically labeled mercury and functionalization of poly-SiNW for detection of dopamine. It is reagents used for Suzuki-Miyaura cross-coupling, induction of pH sensitivity on fluorescence lifetime of quantum dots by NIR fluorescent dyes, bio-supported palladium nanoparticles as phosphine-free catalyst for Suzuki reaction in water and Chan-Lam-type Copper (Cu)-catalyzed S-arylation with aryl boronic acids at room temperature. It is reagents used for the preparation of isoquinolones via regioselective Suzuki-Miyaura cross-coupling and tandem palladium-catalyzed intramolecular aminocarbonylation and annulation, amprenavir-based P1-substituted bi-aryl derivatives as ultra-potent HIV-1 protease inhibitors, phenols via visible-light initiated aerobic oxidative hydroxylation of arylboronic acids using air as oxidant catalyzed by Ruthenium (Ru)-complex, glucose sensitive boronic acid-bearing block copolymers, trisulfonated calixarene upper-rim sulfonamido derivatives and their complexation with the trimethyllysine epigenetic mark. It can also be used as a corrosion inhibitor for steel.

        Reference

        1. Nam, N. D., et al. "A study of 4-carboxyphenylboronic acid as a corrosion inhibitor for steel in carbon dioxide containing environments." Corrosion Science 76.10(2013):257-266.
        2. Vollmueller, Frank, et al. "Cyclization of 4-carboxyphenylboronic acid with hydrazide derivative; hydrolysis; catalytic esterification." US, US 6197967 B1. 2001.

        Chemical Properties

        Off-white to light beige powder

        Uses

        suzuki reaction

        Uses

        Intermediates of Liquid Crystals

        4-Carboxyphenylboronic acid Preparation Products And Raw materials

        Raw materials

        Preparation Products


        4-Carboxyphenylboronic acid Suppliers

        Global( 403)Suppliers
        Supplier Tel Fax Email Country ProdList Advantage
        Boron Technology (Beijing) Co., Ltd. 010-51669040-
        010-51669040 3004509780@qq.com;3004509780@qq.com; China 652 55
        Dafeng Newti Pharmaceutical Technology Co., Ltd. 0512-65916026
        2760994703@qq.com China 296 55
        Shanghai Qinsheng Pharmaceutical Technology Co., LTD. 021-60325517 18321548194
        021-60325517 selinaji@qinvictory.com China 317 58
        Suzhou SuKaiLu Chemical Technology Co., Ltd. +86-512-62766020 15995735907
        +86-512-62766020 zwk@sukailu.com China 1458 55
        Tianshui YiYao Chemical Co., Ltd. 0938-8493022
        0938-8493022 xiaoshi079@163.com China 1047 58
        China Synchem Technology Co.,Ltd. 0552-4929304- ;552-4929304-
        +86-552-4928800 sales@cnsynchem.com;wxh@cnsynchem.com China 36 65
        J & K SCIENTIFIC LTD. 010-82848833- ;010-82848833-
        86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96505 76
        Meryer (Shanghai) Chemical Technology Co., Ltd. 21-61259100-
        86-21-61259102 sh@meryer.com China 40268 62
        Alfa Aesar 400-610-6006; 021-67582000
        021-67582001/03/05 saleschina@alfa-asia.com China 30163 84
        TAIYUAN RHF CO.,LTD. +86 351 7031519
        +86 351 7031519 sales@RHFChem.com China 2348 56

        View Lastest Price from 4-Carboxyphenylboronic acid manufacturers

        Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
        2019-07-26 4-Carboxyphenylboronic acid
        14047-29-1
        US $1.00 / g 1g 99% 9 Ton/Tons per Week Cangzhou Wanyou New Material Technology Co.,Ltd
        2018-08-12 4-Carboxyphenylboronic acid
        14047-29-1
        US $1.00 / KG 1G 99% 100KG career henan chemical co

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